Predicting entropy change from an equation: an interactive particle model. Pick a balanced equation, then raise the reaction progress to watch reactant particles turn into product particles in a closed container, and see whether the number of gas particles, and so the entropy, rises or falls.

You can call the sign of an entropy change without a single number: just count the gas

Entropy is a measure of how spread out particles and their energy are. Gas particles roam the whole container, so they carry far more entropy than a packed solid or a liquid. Pick a reaction, then raise the reaction progress and watch gas particles appear or vanish.

Particle model 0% reacted

Pick a reaction. Raise the progress. Count the gas.

equation

Caption

Reaction progress0%
Gas moles in equation
0 → 1
reactants → products
Predicted ΔS
+
entropy increases
Which rule?

Knowdrop

Know this

A reaction that makes more moles of gas has a positive ΔS; when gas moles do not change, look at the states and particle counts.